Journal of Liaoning Petrochemical University
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The Application of Cyclopentane for Regeneration of  Ionic Liquid Derived from Deep Desulfurization
Wang Shidong, Xu Anqi, Wang Qiang, Zhou Mingdong, Zang Shuliang
Abstract424)      PDF (1361KB)(333)      
The regeneration of thiophene saturated ionic liquid obtained after desulfurization of gasoline were studied. Cyclopentane was used as the extractant to regenerate the ionic liquid( \[C8MIM\] BF4). The dosage of cyclopentane, extraction time and extraction temperature were examined. The optimal operation condition, where V(ionic liquid)∶V(cyclopentane)=1∶2 at 35 ℃ for 15 min were obtained. Under the optimal condition, the backextraction rate of the ionic liquid can reach 8238%. The recovered ionic liquid was further applied to the desulfurization of model oil, and the desulfurization rate can reach 62.37%. 
2015, 35 (3): 15-19. DOI: 10.3696/j.issn.1672-6952.2015.03.004
Sulfides Oxidation Catalyzed by Brnsted Acidic Organic Perrhenates
Qi Shulei, Xu Anqi, Zhou Mingdong, Wang Jingyun, Wang Xin
Abstract414)      PDF (2677KB)(291)      
A series of novel Brnsted acidic organic perrhenates were applied as catalysts for sulfide oxidations using 30% H2O2 as oxidant. The structures and thermal stability data of the catalysts were characterized by FT-IR, NMR and TGA. Meanwhile, the effect of various solvents, the dosage of H2O2 and catalyst, temperature and the reaction time on the catalytic performance was studied in details. The results indicate that the selectivity and yield of sulfoxide can reach up to 95% under the optimal conditions, in which the dosage of catalyst is 0.03 mol, the dosage of H2O2 is 2.4 mmol, 40 ℃ and 90 min.
2015, 35 (3): 1-5,9. DOI: 10.3696/j.issn.1672-6952.2015.03.001